Speculation on my side:
I suppose if your liquid goes out faster than your CO2 comes in, it could maybe happen.
But not if the receiving vessel is higher as then it can only be CO2 pushing out liquid.
Maybe
Both kegs are full, but once ready for use I'll try purge them as it won't do any harm (but I'm trying to save CO2 as it is not readily available).
Would it really be necessary to fill the whole keg with sanitiser? I only got 2 kegs that will be in constant use and no other convenient option to store that much. I mainly just make 2 litres at the time