I've had beers look like those two pictures of white films when fermentation didn't kick off within 24 hours. I never figured out the chemical in question, but those are likely infections. For the two beers that happened, they both tasted and smelled like young (not ripe) pineapple and tasted 'infected' to the point I developed a cough drinking them. I finished one keg and haven't died yet, so perhaps no harm done. (that was 5 years ago) I dumped the second batch.
Also, check out: https://bootlegbiology.com/diy/capturing-yeast/ if you haven't already. It looks like you were trying something like Method #1. It is risky. Since you know you want to capture from the Mandarins, I'd go with Method #2 which is both less chance of baddies, and more likely to only get what you are after rather than a roll of the dice.
Also, check out: https://bootlegbiology.com/diy/capturing-yeast/ if you haven't already. It looks like you were trying something like Method #1. It is risky. Since you know you want to capture from the Mandarins, I'd go with Method #2 which is both less chance of baddies, and more likely to only get what you are after rather than a roll of the dice.