Kai has some great info a bit old but where I did a lot of reading when I was starting out brewing
http://braukaiser.com/wiki/index.php/Starch_Conversion
http://braukaiser.com/wiki/index.php/Starch_Conversion
The glucan conversion makes sense. I agree that with "modern malts" protein rest isn't necessary.I think malt modification is misunderstood. A highly modified malt has been allowed to germinate long enough for the proteins enzymes and betaglucanase to degraded to proteins and glucan to the point so a protein rest or even a glucan rest is not needed. If you have a under modified malt, there still is some proteins and beta glucan that needs to be broken down. This will help with flow in the mash and beer clarity
Highly modified malt does not covert faster than a low modified malt, it just means that mash rests to complete what the maltster failed to complete are not necessary.
But was the temperature relatively consistent over that period of time? If the mash cooled below a certain range, conversion would be affected. If you maintained heat so that mash temp stayed in the peak range, would it matter if it stayed that way for 2 hours or overnight? Almost certainly not. But the difference between 30 minutes at peak conversion temperature and 2 hours would almost certainly give you a significant or at least notable increase in efficiency.I can think of another example of limited conversation time in a few real life examples I've had were I leave the mash for extended periods of time sometimes a couple hours to overnight.
It was still in the saccarafication range I think low 60's.But was the temperature relatively consistent over that period of time? If the mash cooled below a certain range, conversion would be affected. If you maintained heat so that mash temp stayed in the peak range, would it matter if it stayed that way for 2 hours or overnight? Almost certainly not. But the difference between 30 minutes at peak conversion temperature and 2 hours would almost certainly give you a significant or at least notable increase in efficiency.
There you go, in a nutshell! Nice job laying it out HVMEnzymes are affected by temperature. The closer they get to their de-nature temperature, the faster they work. Beta amylase enzyme denatures @149-150F. Alpha amylase denatures @165F or so.
In the real world, it would be best to have those two flipped around, because alpha needs to work before beta can finish the job. Alpha splits the starch molecule down the center and creates lots of "ends". Beta can only work on the "ends" of the molecule, that's why the the alpha needs to go first. So how long does it take to convert depends on temperature. The lower temperatures and pH favors the beta enzyme, but the alpha is also working, but at a slower rate. When you get above 150F, the beta enzymes work the fastest, but are quickly denatured. Alpha continues to work up 168-170F. At those temperatures the alpha enzyme works the fastest, but like beta is quickly denatured.
Beta creates the most fermentable wort, so lower temperature keeps the beta from going away. Beta converts the starches into mostly maltose, sucrose and glucose. Alpha works at the lower temperatures, but again, at a slower rate. Alpha converts starches into dextrin, but it can also produce fermentable sugars like maltose.
Mashes can convert fairly quickly, but the problem lies with the enzymes could still be working on creating simpler sugars or more fermentable wort. So stopping the mash short reduces conversion efficiency and fermentability.
145F mash takes more time 60-90 minutes depending on the beer style.
152F works much faster, but the beta enzyme doesn't last very long, thus less fermentable wort.
158F the mash converts very quickly, but contains more dextrin because the beta didn't have much of a chance to work.
168F is super fast, but alpha is soon disable or denatured.
So why do a mashout? To get the most out of the mash as you can and to a lesser extent, denature amylase enzymes. Mashouts are not necessary. But like I said before, if you can, why not?
Sorry to be so long winded.
I think the useful test would be to compare the 30 minute mash to the 60. It's totally possible, even likely (my observations of apparent increase notwithstanding) that the extra time doesn't yield any significantly better result.I'll still do my regular 60 min ish mash.
But are you willing to dump a batch?I think the useful test would be to compare the 30 minute mash to the 60. It's totally possible, even likely (my observations of apparent increase notwithstanding) that the extra time doesn't yield any significantly better result.
At this point I feel like it's "in for a penny, in for a pound" time-wise. Since any extra time spent mashing or boiling seems fairly small compared to the chunks of time it takes to clean and sort everything before and after the actual brew process, I begrudge any potential or imagined decline in quality that might be attributable to my hurrying things along.
If doing a 30 minute mash is possibly going to cause a batch to be a dumper, then I don't know why we're even discussing the possiblity of full conversion in as little as 15 minutes. Especially given that those of us who are "long mashers" seem to be somewhat in the minority. It would be interesting to see if there was a slightly higher OG in the longer mash but I'd expect to get a perfectly viable beer from a 30 minute mash using typical home-brew malts.But are you willing to dump a batch?
I'd start even lower if a slow rise is your goal. Some Belgian methods include starting at 120 to 130 and raising the temp slowly over a fairly long period of time. That's usually using under-modified brewers malt. For homebrew malt, starting around 144 and raising slowly should probably mimic that method.Wow!! What good infoi!! I think my understanding has increased! I will change my temp profiles and start around 148 degrees and slowly increase the mash to 158. My brew equipment has a heating element that slowly increases heat on recirculation, should take at least an hour to change that temp that much! Looking forward to the next brew!
Thanks everyone!
I guess what I was really meaning was are you willing to compromise the quality of what you're making or change what you're making for an experiment and on a small batch that's fine but if you have something that's proven that's working that 30 minutes really means nothing in the overall scheme of thingsIf doing a 30 minute mash is possibly going to cause a batch to be a dumper, then I don't know why we're even discussing the possiblity of full conversion in as little as 15 minutes. Especially given that those of us who are "long mashers" seem to be somewhat in the minority. It would be interesting to see if there was a slightly higher OG in the longer mash but I'd expect to get a perfectly viable beer from a 30 minute mash using typical home-brew malts.
I got the drift. And, yes, I've stuck with what works with pretty good reason so it's not likely that I'll bother with it but it would be interesting to explore the potential difference.I guess what I was really meaning was are you willing to compromise the quality of what you're making or change what you're making for an experiment and on a small batch that's fine but if you have something that's proven that's working that 30 minutes really means nothing in the overall scheme of things
But at some point it's good to test what points of procedure are really adding up to a better product and which are being held on to basically to avoid jinxing the batch.
@Trialben I have standardized my process to a 45 minute single infusion mash and a 30 minute boil. And this results in….a perfectly clear beer. After running some tests with iodine strips, I found complete conversation around 40 minutes for just about every recipe I make. So I rounded up to 45 to be on the safe side. Most recipes are at 150-152 F.It was still in the saccarafication range I think low 60's.
I used to regularly do this on Saturday mornings mash in then off to Dog training around 9 ish then back home in arvo to continue brew day I didn't notice any better efficiency I left the mash to hang out without heat just incase things went sideways while I was away. Can't remember them beers turning out any thinner in mouthfeel due to extended Beta Amylase activity either. But remember this is my HB bias at play too...
I was listening to brulosophy podcast recently where Marshall was saying his short n shoddy brews happened to suffer from haze my mind shot to unconverted starches some of them mashes are 25mins.
Interesting is it unconverted starches or a short boil or both.
I'll be doing a 30min boil tomorrow but I'll still do my regular 60 min ish mash.
@Bubba Wade you cut back on the boil right?
I wouldn’t mind knocking off some time on my brew day, especially if I was only wasting that time to begin with.