Chlorine definitely evaporates overnight, and can easily be driven out by boiling. Chloramine, however, is somewhat more persistent: it doesn't come out by itself. That half campden tablet eliminates chloramine instantly.Any kind of water filter meant to eliminate chlorine will reduce 95%+ Instantly. The remaining <5% is probably negligible. Also, chlorine evaporates fairly rapidly when left in an open container. My practice is to fill my AIO the night before and leave it open. But, for cheap insurance I do add a 1/2 campden tablet.