I had read on a forum a debate on leaving Star-San in the keg for storage on whether it was safe or not to the stainless keg. I emailed them (5 Star Chemicals), and their response was that they do not recommend it, with no further explanation, and I never replied back. Since then, I One Step clean, then Star-San (half hour each in a keg washer), then let them air dry with the lids partly on so it can breathe, then Star-San rinse and hold prior to filling.
Edit: My thinking was that if there’s even the slightest flaw in the SS or the SS weld, that the acid wouldn’t be friendly to the metal.