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Is the bucket left open, without a lid? I keep my starsan mixture in 4 liter jugs, and for sure it lasts indefinitely.I've kept a bucket of it in my garage for months without issue, so I'm guessing long enough.
Interesting, I would have thought that the pH would just balance out over time if left in an open top container. I have nothing to base this on, just a conclusion I was jumping to.If anything, the evaporation should make the solution more concentrated. I don't see any reason to worry about effective pH unless you're mixing with very alkaline water.