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Heard a fascinating other way of thinking of decoction mashing the other day. German Berliner Weisse nerd was asked about whether to do decoction for a 'historically accurate' Berliner Weisse. He didn't think it was that important, but then went on to explain the genesis of decoction mashing as he sees it...
Brewers in the 18th century couldn't afford anything more than a small copper kettle, but they new if you wanted bitterness from your hops you had to boil the water. So to get decent bitterness in a big batch that you're mashing in a wooden tun you take out a thin part of the mash, add the hops to that and boil it. So for him decoction is an old approach to getting isomerisation when you couldn't afford a metal boil kettle. He didn't really see the caramalisation/maillard reaction stuff as part of the reason for decoction.
This was on the latest milk the funk podcast.
Brewers in the 18th century couldn't afford anything more than a small copper kettle, but they new if you wanted bitterness from your hops you had to boil the water. So to get decent bitterness in a big batch that you're mashing in a wooden tun you take out a thin part of the mash, add the hops to that and boil it. So for him decoction is an old approach to getting isomerisation when you couldn't afford a metal boil kettle. He didn't really see the caramalisation/maillard reaction stuff as part of the reason for decoction.
This was on the latest milk the funk podcast.